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锌基金属有机框架材料对三甲胺的吸附性能研究

吕道飞 林洁玲 许锋 袁文兵 张妍 陈忻

吕道飞, 林洁玲, 许锋, 袁文兵, 张妍, 陈忻. 锌基金属有机框架材料对三甲胺的吸附性能研究[J]. 南方水产科学. doi: 10.12131/20220160
引用本文: 吕道飞, 林洁玲, 许锋, 袁文兵, 张妍, 陈忻. 锌基金属有机框架材料对三甲胺的吸附性能研究[J]. 南方水产科学. doi: 10.12131/20220160
LYU Daofei, LIN Jieling, XU Feng, YUAN Wenbing, ZHANG Yan, CHEN Xin. Study on adsorption performance of zinc-based metal-organic framework for trimethylamine[J]. South China Fisheries Science. doi: 10.12131/20220160
Citation: LYU Daofei, LIN Jieling, XU Feng, YUAN Wenbing, ZHANG Yan, CHEN Xin. Study on adsorption performance of zinc-based metal-organic framework for trimethylamine[J]. South China Fisheries Science. doi: 10.12131/20220160

锌基金属有机框架材料对三甲胺的吸附性能研究

doi: 10.12131/20220160
基金项目: 国家自然科学基金项目 (22108034);广东省基础与应用基础研究基金联合基金项目 (2020A1515110945);广东省海洋经济发展 (海洋六大产业) 专项资金 (粤自然资合〔2020〕036号);佛山市新型多孔材料工程技术研究中心 (2020001003999)
详细信息
    作者简介:

    吕道飞 (1993—),男,讲师,博士,从事多孔材料脱腥除臭研究。E-mail: 473766259@qq.com

    通讯作者:

    陈 忻 (1968—),女,教授,博士,从事高端海洋生物化妆品研发。E-mail: chenxin@fosu.edu.cn

  • 中图分类号: S 985.2

Study on adsorption performance of zinc-based metal-organic framework for trimethylamine

  • 摘要: 海产品富含蛋白质等多种活性物质,广泛用于食品和化妆品行业。如何高选择性地脱除海产品中三甲胺 (TMA) 等腥味物质,是目前海产品加工过程中面临的难题。通过X射线粉末衍射、扫描电子显微镜等对沸石咪唑骨架材料-8 (ZIF-8)、美孚石油公司5号沸石 (ZSM-5) 分子筛和活性氧化铝材料进行表征,研究了这3种材料对典型腥味物质三甲胺的吸附性能。吸附动力学测试表明,在200 mg·L−1的三甲胺溶液中,3种吸附剂在600 min左右达到吸附饱和。测试3种吸附剂在25 ℃下的吸附等温线,发现它们对三甲胺的吸附容量为:ZIF-8 (517.1 mg·g−1) >活性氧化铝 (401.8 mg·g−1) > ZSM-5 (390.3 mg·g−1)。同等条件下,ZIF-8对三甲胺的吸附量是活性炭的3.2倍,其吸附性能超过同期的大多数材料。傅里叶变换红外光谱和Zeta电位测试表明,ZIF-8和三甲胺间的吸附作用为C-H···π作用和C-H···N作用及静电作用。
  • 图  1  ZIF-8的PXRD图谱

    Figure  1.  PXRD patterns of ZIF-8

    图  2  ZSM-5 (a) 和活性氧化铝 (b) 的实验PXRD图谱

    Figure  2.  Experimental XRD patterns of ZSM-5 (a) and activated alumina (b)

    图  3  在77 K下吸附剂对N2的吸附脱附等温线 (a) 和吸附剂的孔径分布图(b)

    Figure  3.  Adsorption and desorption isotherm of N2 by adsorbent (a) and pore size distribution of adsorbent (b) at 77 K

    图  4  在×5万放大倍率下ZIF-8的SEM显微照片

    Figure  4.  SEM images of ZIF-8 at ×50 000 magnification

    图  5  ZIF-8 (a)和(b) , ZSM-5(c) 和活性氧化铝 (d) 吸附前、吸附后和三甲胺的红外谱图

    Figure  5.  Infrared spectra of ZIF- 8 (a), (b), ZSM-5(c) and activated alumina (d) before and after adsorption of trimethylamine

    图  6  ZIF-8、ZSM-5和活性氧化铝的吸附动力学曲线

    Figure  6.  Adsorption kinetic curves of ZIF-8, ZSM-5 and activated alumina

    图  7  ZIF-8、ZSM-5和活性氧化铝的伪二级动力学模型拟合结果

    Figure  7.  Fitting results of pseudo second-order kinetic model for ZIF-8, ZSM-5 and activated alumina

    图  8  ZIF-8、ZSM-5和活性氧化铝在25 ℃下的吸附等温线

    Figure  8.  Adsorption isotherms of ZIF-8, ZSM-5 and activated alumina at 25 ℃

    图  9  吸附温度对 ZIF-8,ZSM-5 和活性氧化铝吸附200 mg·L−1三甲胺吸附量的影响

    Figure  9.  Effect of temperature on adsorption performance of trimethylamine (200 mg·L−1) on ZIF-8, ZSM-5 and activated alumina

    图  10  ZIF-8、ZSM-5和活性氧化铝的循环再生性能

    Figure  10.  Regeneration performance of ZIF-8, ZSM-5 and activated alumina

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  • 收稿日期:  2022-06-07
  • 修回日期:  2022-07-18
  • 录用日期:  2022-07-19
  • 网络出版日期:  2022-07-23

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